Design of hydrophilic MOF water adsorbents for heat reallocation

by A. Cadiau, J. S. Lee, D. Damasceno-Borges, P. Fabry, T. Devic, M.T. Wharmby, C. Martineau, D. Fouchet, F. Taulelle, C.-H. Jun, Y. K. Hwang, N. Stock, M. F. De Lange, F. Kapteijn, J. Gascon, G. Maurin, J. S. Chang, C. Serre

Year: 2015 ISSN: DOI: 10.1002/adma.201502418

Bibliography

A. Cadiau, J. S. Lee, D. Damasceno-Borges, P. Fabry, T. Devic, M.T. Wharmby, C. Martineau, D. Fouchet, F. Taulelle, C.-H. Jun, Y. K. Hwang, N. Stock, M. F. de Lange, F. Kapteijn, J. Gascon, G. Maurin, J. S. Chang, C. Serre, Adv. Mater. 27 (2015) 4775-4780, Design of hydrophilic MOF water adsorbents for heat reallocation

Abstract

A new hydrothermally stable Al polycarboxylate metal–organic framework (MOF) based on a heteroatom bio-derived aromatic spacer is designed through a template-free green synthesis process. It appears that in some test conditions this MOF outperforms the heat reallocation performances of commercial SAPO-34.

Keywords

Aluminium carboxylate Heat transfer Metal–organic-frameworks Porosity Water sorption