NH2-MIL-53(Al): a high contrast reversible solid state non-linear optical switch

by P. Serra-Crespo, M. A. Van Der Veen, E. Gobechiya, K. Houthoofd, Y. Filinchuk, C.E.A. Kirschhock, J.A. Martens, B.F. Sels, D.E. De Vos, F. Kapteijn, J. Gascon

Year: 2012 ISSN: DOI: 10.1021/ja300655f

Bibliography

P. Serra-Crespo, M. A. van der Veen, E. Gobechiya, K. Houthoofd, Y. Filinchuk, C.E.A. Kirschhock, J.A. Martens, B.F. Sels, D.E. De Vos, F. Kapteijn, J. Gascon, J. Am. Chem. Soc. 134, (2012), 8314–8317, NH2-MIL-53(Al): a high contrast reversible solid state non-linear optical switch

Abstract

The metal–organic framework NH₂-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

Keywords

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