Highly selective chemical sensing in a luminescent nanoporous magnet

by J. Ferrando-Soria, H. Khajavi, P. Serra-Crespo, J. Gascon, F. Kapteijn, M. Julve, F. Lloret, J. Pasán, C. Ruiz-Pérez, Y. Journaux, E. Pardo

Year: 2012 ISSN: DOI: 10.1002/adma.201201846

Bibliography

J. Ferrando-Soria, H. Khajavi, P. Serra-Crespo, J. Gascon, F. Kapteijn, M. Julve, F. Lloret, J. Pasán, C. Ruiz-Pérez, Y. Journaux, E. Pardo, Adv. Mat. 24 (2012) 5625-5629, Highly selective chemical sensing in a luminescent nanoporous magnet

Abstract

On the road to chemical sensors: A novel 2D oxamato-based manganese(II)-copper(II) mixed-metal–organic framework (M'MOF) exhibiting non-linear fluorescence and long-range magnetic ordering is reported. This new luminescent nanoporous magnet features highly selective solvent- and gas sorption-induced optical switching behavior, opening the door to potential application for sensing of small molecules.

Keywords

Methylviologen Metal–organic frameworks Molecule-based magnets Luminescent properties Chemosensors