2012

Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework

​J. Ferrando-Soria , P. Serra-Crespo , M. de Lange , J. Gascon , F. Kapteijn , M. Julve , J. Cano , F. Lloret , J. Pasan , C. Ruiz-Perez , Y. Journaux , E. Pardo, J. Am. Chem. Soc. 134 (2012) 15301–15304, Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework
J. Ferrando-Soria, P. Serra-Crespo, M. de Lange, J. Gascon, F. Kapteijn, M. Julve, J. Cano, F. Lloret, J. Pasan, C. Ruiz-Perez, Y. Journaux, E. Pardo
N/A
2012
​A novel isoreticular oxamato-based manganese(II)–copper(II) open metal–organic framework H2O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO2 over CH4) and vapor molecules (CH3OH over CH3CN and CH3CH2OH). H2O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [TC < 2.0 K (CO2@iso1 and CH4@iso1) and TC = 6.5 (CH3OH@iso1) and 21.0 K (H2O@iso1)].
DOI: 10.1021/ja3045822